1  Cover

      2  Title Page

      3  Copyright Page

      4  Preface

      5  List of Contributors

      6  Acknowledgements

      7  1 The Road to Aromatic Functionalization by Mixed‐metal Ate Chemistry 1.1 Introduction 1.2 Deprotonation of Aromatics 1.3 Aromatic Ate Complex Chemistry: Metal/Halogen Exchange 1.4 Deprotonation Using Ate Complexes 1.5 Concluding Remarks References

      8  2 Structural Evidence for Synergistic Bimetallic Main Group Bases 2.1 General Introduction 2.2 Homometallic Bases 2.3 Heterometallic Bases 2.4 Outlook References

      9  3 Turbo Charging Group 2 Reagents for Metathesis, Metalation, and Catalysis 3.1 Introduction and Historical Context: Monometallic s‐block Reagents and Their Utility 3.2 Heterobimetallic Reagents for Selective Metalation 3.3 Homogeneous Catalysis by s‐block Reagents 3.4 Outlook: Turbo Charging the Turbo Reagents and Prospects for Catalysis References

      10  4 Mechanisms in Heterobimetallic Reactivity 4.1 Introduction and Scope of the Chapter 4.2 Small Molecule Activation and Catalysis 4.3 Polymerization Catalysis 4.4 Conclusion References

      11  5 Cationic Compounds of Group 13 Elements 5.1 Introduction 5.2 General Considerations 5.3 Recent Developments in Cationic Group 13 Complexes 5.4 Recent Advancements in Catalytic Applications of Cationic Group 13 Complexes 5.5 Concluding Remarks References

      12  6 Recent Development in the Solution Structural Chemistry of Main Group Organometallics 6.1 Introduction 6.2 Monometallic Systems 6.3 Heteropolymetallic Systems 6.4 Concluding Remarks References

      13  7 Chemistry of Boryl Anions 7.1 Introduction 7.2 Boryl Anions as a Salt of Alkali Metals 7.3 Boryl Anions as a Salt of Magnesium, Zinc, and Copper as Relatives of Carbanions 7.4 Application of Borylcopper and Borylzinc Species for Synthetic Organic Chemistry 7.5 Summary References

      14  8 Novel Chemical Transformations in Organic Synthesis with Ate Complexes 8.1 Introduction 8.2 Ate Complexes 8.3 Di‐anion‐type Zincate 8.4 Heteroleptic Zinc Ate Complexes 8.5 Conclusion References

      15  9 Isolable Alkenylcopper Compounds 9.1 Introduction 9.2 Well‐defined Alkenylcopper Compounds 9.3 Summary References

      16  Index

      17  End User License Agreement

      1 Chapter 2Table 2.1 Effect of identity of alkali metal alkoxide on yield and meta/par...

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