Henley's Twentieth Century Formulas, Recipes and Processes. Various
Читать онлайн книгу.
and patented in Germany, is composed of 10 pounds each of train oil, horse fat, paraffine, and of finely ground zinc white. To this mixture is added 40 pounds of graphite and 10 pounds of soot made together into a paste with 1 1/2 gallons of water, and about a pound of carbolic acid. The horse fat and the zinc oxide make a soap difficult to fuse, which adheres strongly to the plates, and binds the graphite and the soot. The paraffine prevents the water from penetrating the coats. The scale which forms on this application can be detached, it is said, with a wooden mallet, without injuring the paint.
VII.—M. E. Asselin, of Paris, recommends the use of glycerine as a preventive. It increases the solubility of combinations of lime, and especially of the sulphate. It forms with these combinations soluble compounds. When the quantity of lime becomes so great that it can no longer be dissolved, nor form soluble combinations, it is deposited in a gelatinous substance, which never adheres to the surface of the iron plates. The gelatinous substances thus formed are not carried with the steam into the cylinder of the engine. M. Asselin advises the employment of 1 pound of glycerine for every 300 pounds or 400 pounds of coal burnt.
Prevention Of Electrolysis.
—In order to prevent the eating away of the sheets and tubes by electrolytic action, it has long been the practice of marine engineers to suspend slabs of zinc in their boilers. The zinc, being more susceptible to the electrolytic action than the iron, is eaten away, while the iron remains unimpaired. The use of zinc in this way has been found also to reduce the trouble from boiler scale. Whether it be due to the formation of hydrogen bubbles between the heating surfaces and incipient scale, to the presence in the water of the zinc salts resulting from the dissolution of the zinc, or to whatever cause, it appears to be a general conclusion among those who have used it that the zinc helps the scale, as well as the corrosion. Nobody has ever claimed for it that it prevented the attachment of scale altogether, but the consensus of opinion is that it “helps some.”
Boiler Pressure.
It hardly pays to reduce pressure on boilers, except in very extreme cases, but if it can be done by throttling before the steam reaches the cylinder of the engine it would be an advantage, because this retains the heat units due to the higher pressure in the steam, and the throttling has a slight superheating effect. As a matter of fact, tests go to show that for light loads and high pressure a throttling engine may do better than an automatic cut-off. The ideal arrangement is to throttle the steam for light loads; for heavier loads, allow the variable cut-off to come into play. This practice has been carried into effect by the design of Mr. E. J. Armstrong, in which he arranges the shaft governor so that there is negative lead up to nearly one-quarter cut-off, after which the lead becomes positive, and this has the effect of throttling the steam for the earlier loads and undoubtedly gives better economy, in addition to making the engine run more quietly.
BONE BLACK:
Bone Or Ivory Black.
—All bones (and ivory is bone in a sense) consist of a framework of crystallized matter or bone earth, in the interstices of which organic matter is embedded. Hence if {124} bones are heated red-hot in a closed vessel, the organic matter is destroyed, leaving carbon, in a finely divided state, lodged in the bony framework. If the heat is applied gradually the bone retains its shape, but is quite black and of much less weight than at first. This bone black or animal charcoal is a substance which has great power of absorbing coloring matter from liquids, so that it is largely used for bleaching such liquids. For example, in the vast industry of beet-sugar manufacture the solutions first made are very dark in color, but after filtration through animal charcoal will give colorless crystals on evaporation. Chemical trades require such large quantities of bone charcoal that its production is a large industry in itself. As in breaking up the charred bones a considerable amount of waste is produced, in the form of dust and small grains which cannot be used for bleaching purposes, this waste should be worked up into a pigment. This is done by dissolving out the mineral with hydrochloric acid, and then rinsing and drying the carbon.
The mineral basis of bones consists mainly of the phosphates of lime and magnesia, salts soluble in not too dilute hydrochloric acid. A vat is half filled with the above-mentioned waste, which is then just covered with a mixture of equal volumes of commercial hydrochloric acid and water. As the mineral matter also contains carbonates, a lively effervescence at once ensues, and small quantities of hydrofluoric acid are also formed from the decomposition of calcium fluoride in the bones. Now hydrofluoric acid is a very dangerous substance, as air containing even traces of it is very injurious to the lungs. Hence the addition of hydrochloric acid should be done in the open air, and the vat should be left by itself until the evolution of fumes ceases. A plug is then pulled out at the bottom and the carbon is thoroughly drained. It is then stirred up with water and again drained, when it has fully settled to the bottom. This rinsing with clear water is repeated till all the hydrochloric acid is washed away and only pure carbon remains in the vat. As for pigment-making purposes it is essential that the carbon should be as finely divided as possible, it is as well to grind the washed carbon in an ordinary color mill. Very little power is required for this purpose, as when once the bone earth is removed the carbon particles have little cohesion. The properly ground mass forms a deep-black mud, which can be left to dry or be dried by artificial heat. When dry, the purified bone black is of a pure black and makes a most excellent pigment.
Bone black is put upon the market under all sorts of names, such as ivory black, ebur ustum, Frankfort black, neutral black, etc. All these consist of finely ground bone black purified from mineral matter. If leather scraps or dried blood are to be worked up, iron tubes are employed, closed at one end, and with a well-fitting lid with a small hole in it at the other. As these bodies give off large volumes of combustible gas during the charring, it is a good plan to lead the vapors from the hole by a bent tube so that they can be burnt and help to supply the heat required and so save fuel. Leather or blood gives a charcoal which hardly requires treatment with hydrochloric acid, for the amount of mineral salts present is so small that its removal appears superfluous.
BONES, A TEST FOR BROKEN.
Place a stethoscope on one side of the supposed fracture, and a tuning fork on the other. When the latter is vibrated, and there is no breakage, the sound will be heard distinctly through bone and stethoscope. Should any doubt exist, comparison should be made with the same bone on the other side of the body. This test shows the difference in the power of conducting sound possessed by bone and soft tissue.
BONE BLEACHES: See Ivory.
BONE FAT: See Fats.
BONE FAT, PURIFICATION AND BLEACHING OF: See Soap.
BONE POLISHES: See Polishes.
BONE FERTILIZERS: See Fertilizers.
BONES, TREATMENT OF, IN MANUFACTURING GLUE: See Adhesives.
BONE, UNITING GLASS WITH: See Adhesives.
BOOKS, THEIR HANDLING AND PRESERVATION:
The Preservation Of Books In Hot Climates.
—Books in hot climates quickly deteriorate unless carefully guarded. There are three destructive agencies: (1) damp, (2) a small black insect, (3) cockroaches. {125}
(1) Books which are kept in a damp atmosphere deteriorate on account of molds and fungi that grow rapidly when the conditions are favorable. Books are best kept on open, airy, well-lighted shelves.