1  Cover

      2  Title Page

      3  Copyright

      4  Foreword

      5  Preface

      6  1 IR Spectra in Space Observation 1.1. Introduction 1.2. Fourier transform spectroscopy 1.3. Resonant cavity laser absorption spectroscopy 1.4. Spectroscopy for space observation 1.5. Conclusion 1.6. Appendices

      7  2 Interactions Between a Molecule and Its Solid Environment 2.1. Introduction 2.2. Active molecule – solid environment system 2.3. Two-center expansion of the term

      8  3 Nanocage of Rare Gas Matrix 3.1. Introduction 3.2. Rare gases in solid state 3.3. Molecule inclusion and deformation of the doped crystal 3.4. Motions of NH₃ trapped in an argon matrix 3.5. Infrared spectra 3.6. Appendices

      9  4 Nanocages of Hydrate Clathrates 4.1. Introduction 4.2. The extended substitution model 4.3. Clathrate structures 4.4. Inclusion of a CH₄ or NH₃ molecule in a clathrate nanocage 4.5. System Hamiltonian and separation of movements 4.6. Translational motion 4.7. Vibrational motions 4.8. Orientational motion 4.9. Bar spectra 4.10. Appendices

      10  5 Fullerene Nanocage 5.1. Introduction 5.2. Ammonia molecule trapped in a fullerene C₆₀ nanocage 5.3. Potential energy surfaces – inertial model 5.4. Quantum treatment 5.5. Bar spectra 5.6. Appendices

      11  6 Adsorption on a Graphite Substrate 6.1. Introduction 6.2. “NH₃ molecule–substrate” system interaction energy 6.3. Equilibrium configuration and potential energy surfaces 6.4. Hamiltonian of the system 6.5. Infrared spectra of the NH₃ molecule adsorbed on the graphite substrate 6.6. Conclusion 6.7. Appendices

      12  References

      13  Index

      14  End User License Agreement

      1 Chapter 1Figure 1.1. Interferometer diagram. For a color version of this figure, see www....Figure 1.2. Experimental setup for laser spectroscopy: induced fluorescence and ...Figure 1.3. Experimental setup of the cryostat headFigure 1.4. FTIR spectrometer and experimental setup. For a color version of thi...Figure 1.5. O3 region ν3: (a) HF double site and (b) BF simple site (gas: 1042.0...Figure 1.6. CO2 region ν2: (a) BF stable site and (b) HF unstable site (gas: 648...Figure 1.7. N2O region ν2: double site (gas: 588.77 cm–1)Figure 1.8. Nd-Yag laser: (1) cavity bottom mirror (Rmax = 1,064 nm), (2) shutte...Figure 1.9. Dye laser, cavities, optical elements and mixer crystal LiNbO3Figure 1.10. Global fluorescence: (a) stable site and (b) unstable site, Ar/13CO...Скачать книгу