1  Cover

      2  Title Page

      3  Copyright

      4  List of Illustrations

      5  List of Tables

      6  List of Schemes

      7  Preface

      8  Abbreviations

      9  1 Introduction: A Brief Introduction About Metal-Organic Frameworks 1.1 Metal-Organic Frameworks 1.2 Conclusion References

      10  2 Metal-Organic Frameworks Complexity 2.1 Perspectives on Complexity in MOFs 2.2 Conclusion References

      11  3 Complexity Based on Ligand—Part 1 3.1 Mixed Ligand 3.2 Conclusion References

      12  4 Complexity Based on Ligand—Part 2 4.1 Polytopic Linkers 4.2 Multi-Heterotopic Ligands 4.3 Conclusion References

      13  5 Complexity Based on Metal Node 5.1 Mixed Metal 5.2 Multiple SBUs 5.3 Conclusion References

      14  6 Complexity Based on Chiral Framework—Part 1 6.1 Inherent Chirality 6.2 Direct Chirality 6.3 Conclusion References

      15  7 Complexity Based on Chiral Framework—Part 2 7.1 Chiral-Template Synthesis 7.2 Post-Synthesis 7.3 Conclusion References

      16  8 Complexity Based on Structural Defects 8.1 Inherent Defect 8.2 Designed Defect 8.3 Conclusion References

      17  9 Complexity Based on Heterogeneous Pores 9.1 Heterogeneous Pores 9.2 Conclusion References

      18  10 Complexity Based on Mixed MOFs 10.1 Complex Mixed MOFs 10.2 Conclusion References

      19  Index

      20  Also of Interest

      21  End User License Agreement

      1 Chapter 3Table 3.1 Examples of mixed ligands metal-organic frameworks.Table 3.2 Determination of catalytic conditions for Biginelli reaction.

      2 Chapter 5Table 5.1 Optimization of the carboxylation of phenylacetylene^a.Table 5.2 Carboxylation of terminal alkynes with CO₂^a.Table 5.3 Crystallographic data and refinement parameters of the considered MOF.Table 5.4 Various applications of mixed-metal MOFs.

      3 Chapter 6Table 6.1 Diethylzinc additions to aromatic aldehydes.Table 6.2 Alkynylzinc additions to aromatic aldehydes (similar conditions with T...

      4 Chapter 7Table 7.1 Asymmetric dihydroxylation of aryl olefins.^aTable 7.2 Aldol reactions catalyzed by Zn-MOF1.^aTable 7.3 Aldol reactions by using Zn-MOF1 and Zn-MOF2.Table 7.4 Control reactions for asymmetric epoxidation of styrene.^aTable 7.5 Asymmetric epoxidation of several olefins and methanolysis of styrene ...

      5 Chapter 8Table 8.1 Some of the published papers about defects in metal-organic frameworks...Table 8.2 Some of defective MOF-based materials.

      6 Chapter 10Table 10.1 Carbon dioxide cycloaddition with various epoxides by using CZ-BDO.^a

      1 Chapter 1Figure